Material Safety Data Sheet
Product No. 18394 Paraplast® X-TRA
Issue Date (02-14-06)
Review Date (04-25-07)
Section 1: Product and Company Identification
Product Name: Paraplast® X-TRA
Synonym: None
Manufacturer/Supplier: McCormick Scientific LLC, St. Louis, MO 63134
Company Name
Ted Pella, Inc. and PELCO International, P.O. Box 492477, Redding, CA
96049-2477
Domestic Phone (800) 237-3526 (Mon-Thu. 6:00AM to 4:30PM PST; Fri 6:00AM
to 4:00PM PST)
International Phone (01) (530) 243-2200 (Mon-Thu. 6:00AM to 4:30PM PST; Fri 6:00AM to 4:00PM PST)
Chemtrec Emergency Number 1-800-424-9300 24 hrs a day.
Section 2: Composition / Information on Ingredients
|
Principle Hazardous Component(s)
|
% |
OSHA mg/m3 |
ACGIH |
NTP |
IARC |
OSHA |
|
Paraffin (Paraffin Wax) (8002-74-2) |
>75 |
2* |
2* |
No |
No |
No |
|
Resin (Proprietary) |
<25 |
NE |
NE |
No |
No |
No |
|
Butylated Hydroxy Toluene (p-Cresol, 2, 6-Di-tert-Butyl) (128-37-0) |
~1 |
ND |
2 |
No |
No |
No |
* The Occupational Safety and Health Administration (OSHA) and the American
Conference of Governmental Industrial Hygienists (ACGIH) have not established
exposure limits for this product. However, exposure limits do exist for the primary
hazardous ingredient, which is present at greater than 90%: Paraffin
(8002-74-2) fumes.
Section 3: Hazard Identification
Emergency overview
EU Main Hazards: Not classified as hazardous.
Appearance: Waxy pellets
Immediate effects: This product is a mixture for which no health effects data exists. The information provided below represents a comprehensive overview of the effects of the individual ingredients; therefore, the actual hazards of the product may be overestimated. Since no health effects information was available for polyisobutylene, microcrystalline wax, or hydrocarbon resin, the hazards described below represent the health effects associated with paraffin, the product's primary ingredient.
Potential health effects
Primary Routes of entry: Skin,
eyes, and inhalation.
Signs and Symptoms of Overexposure:
Eyes: May cause mild eye irritation.
Skin: May cause mild skin irritation.
Ingestion: The product is not expected to present a hazard from ingestion. No data were available on the health effects of paraffin from this route of exposure.
Inhalation: Inhalation of paraffin wax fumes (for example, when the wax is heated) may irritate the eyes, nose, and throat.
Chronic Exposure: May cause dermatitis with skin irritation and rash.
Chemical Listed As Carcinogen Or Potential Carcinogen: No human or animal data were available on the carcinogenic effects following oral or inhalation exposure. However, when implanted in experimental animals, paraffin caused tumors of the bladder and of the respiratory system.
See Toxicological Information (Section11)
Potential environmental effects
See Ecological Information (Section 12)
Section 4: First Aid Measures
If accidental overexposure is suspected
Eye(s) Contact: First check the victim for contact lenses and remove if present. Immediately flush eyes with plenty of water or normal saline for at least 15 minutes while holding eyelids open. If symptoms such as redness or irritation develop or persist, get immediate medical attention. Do not put any medication in the victim's eyes unless instructed by a physician.
Skin Contact: Remove and isolate
contaminated clothing. Wash skin with soap and flush thoroughly with plenty of
water. Obtain medical attention if irritation develops, or other symptoms
occur. Clean contaminated clothing before re-use, or dispose of properly.
Inhalation: Remove exposed subject to fresh air. If not breathing, perform
artificial respiration. If breathing is difficult, administer oxygen (by
trained personnel only). Keep subject warm. Get immediate medical attention.
Ingestion: If swallowed, do NOT induce vomiting. If the subject is conscious, give them 1 or 2 glasses of water to dilute the chemical. Call a physician or poison control center immediately. Never give anything by mouth to an unconscious person. If the victim is unconscious, keep their airway open and lay the victim on their side with the head lower than the body. Get immediate medical attention.
Note to physician
Treatment: ND
Medical Conditions generally Aggravated by Exposure: No data are available on the medical conditions aggravated by exposure to this product or its primary ingredient.
Section 5: Fire Fighting Measures
Flash Point: 400 °F (201 °C) Method: Closed Cup
Flammable Limits: ND
Auto-ignition point: 473 °F (245
°C) (for 100% paraffin)
Fire Extinguishing Media: For fires involving this product or its packaging
material, use an extinguisher which is appropriate for combustibles and
surrounding class(es) of fire.
Special Fire Fighting Procedures: Keep unnecessary people away; isolate hazard
area and deny entry. Remove containers exposed to fire if possible, otherwise
cool them from the side with water spray. Emergency equipment including
self-contained breathing apparatus (SCBA) and full fire fighting turnout gear
should be worn by fire fighters.
Unusual Fire and Explosion Hazards: ND
Hazardous combustion products: Fires of paraffin wax may produce toxic fumes.
DOT Class: Not regulated
Section 6: Accidental Release
Measures
Steps to be Taken in Case Material is Released or Spilled: Follow
facility-specific procedures for spill response. Isolate the spill area. When
cleaning spills, wear appropriate personal protective equipment including:
safety glasses and chemical resistant gloves. Confine and contain small spills
using inert material (e.g. paper towels, spill control pillows). If the wax is
hot, let cool before initiating clean-up. To clean-up spills of cooled wax, use
non-sparking tools to scrape the wax into containers suitable for disposal.
Waste Disposal Methods: Dispose of waste according to Federal, State and Local
Regulations.
Section 7: Handling and Storage
Precautions to be Taken in Handling and Storage: Keep containers closed when
not in use. Store in a cool, dry, well-ventilated area.
Storage temperature: ND
Storage Pressure: ND
Section 8: Exposure Controls / Personal Protection
Engineering Controls
Ventilation required: Good general room ventilation expected to be adequate to control airborne levels. If certain operations generate vapors or fumes (i.e., heating the paraffin), use adequate general or local ventilation to keep airborne concentrations below exposure limits.
Personal Protection Equipment
Respiratory protection: A respirator is not required under normal conditions of use if exposure limits are kept below those listed under exposure guidelines.
Protective gloves: Wear
impervious gloves to prevent skin contact.
Skin protection: Lab coat, apron or other impermeable clothing may be
appropriate.
Eye protection: Safety glasses with side shields or goggles
Additional clothing and/or equipment: ND
Exposure Guidelines
Paraffin wax:
ACGIH: TLV 2 mg/M3 8 hr. TWA (fume).
UK EH40: OES 2 mg/M3 8 hr. TWA
UK EH40: OES 6 mg/M3 10 min. TWA
Resin: None assigned.
Butylated hydroxytoluene: ACGIH TLV: 2 mg/M3 (8 hr. TWA)
See Composition/Information on Ingredients (Section2)
Section 9 Physical and
Chemical Properties
Appearance and Physical State: Colorless or white, translucent, solid pellet
Odor (threshold): No odor
Specific Gravity (H2O=1): 0.82
Vapor Pressure (mm Hg): ND
Vapor Density (air=1): ND
Percent Volatile by volume: NA
Evaporation Rate (butyl acetate=1): NA
Boiling Point: ND
Freezing point / melting point:
117 – 149 °F (47 – 65 °C), depending on grade.
pH: ND
Solubility in Water: Insoluble. Other: Insoluble in alcohol, soluble in
benzene, chloroform, ether, carbon disulfide, and oils; miscible with fats.
Molecular Weight: ND
Section 10: Stability and Reactivity
Stability: Stable under normal conditions of use and when stored at room
temperature.
Conditions to Avoid: Heat, high temperatures, pressure, mechanical shock or
other conditions that might result in a hazardous situation.
Materials to Avoid (Incompatibility):
There are no known materials which are incompatible with this product. Paraffin
is incompatible with strong reducing agents and strong acids.
Hazardous Decomposition Products: Fires of paraffin wax may produce toxic
fumes.
Hazardous Polymerization: Will not occur
Section 11: Toxicological Information
Results of component toxicity test performed: This product is a mixture for which no toxicological data exists. When available, toxicological data for the product's hazardous ingredients are provided. Hydrocarbon Resin (6472-16-1), (Ingestion, Mammal): LD50 = 7 mg/kg. Paraffin (8002-74-2), (Eyes, Rabbit) = A 100 mg dose applied to the rabbit eye for 24 hours caused mild irritation. Paraffin (8002-74-2), (Skin, Rabbit) = A 500 mg dose applied to rabbit skin for 24 hours caused mild irritation. Carcinogenic Effects Data: Paraffin (8002-74-2): When implanted in rats (120 mg/kg) and mice (480-660 mg/kg), caused tumors of the bladder, lungs, and thorax.
Human experience: ND
This product does not contain any compounds listed by NTP or IARC or regulated by OSHA as a carcinogen.
Section 12: Ecological Information
Ecological Information: No data available for the product or its hazardous ingredients.
Chemical Fate Information: No data available for the product or its hazardous ingredients.
Section 13 Disposal Considerations
RCRA 40 CFR 261 Classification: Not listed
Federal, State and local laws governing disposal of materials can differ. Ensure proper disposal compliance with proper authorities before disposal.
Section 14: Transportation Information
US DOT Information: Proper shipping name: Not regulated
IATA: Proper shipping name: Not regulated
Domestic shipments only:
IMO: Proper shipping name: Not regulated
Marine Pollutant: ND
Canadian TDG: This product is not regulated under international transportation regulations.
Section 15: Regulatory Information
United States Federal Regulations
MSDS complies with OSHA’s Hazard Communication Rule 29, CFR 1910.1200.
SARA: No
SARA Title III: This product does not contain a chemical that is listed in Section 313 at or above de minimis concentrations.
RCRA: Not listed
TSCA: Materials in this product are listed on the EPA TSCA Chemical Inventory.
CERCLA: Not listed
State Regulations
California Proposition 65: This product does not contain materials which the State of California has found to cause cancer, birth defects or other reproductive harm.
Massachusetts: Massachusetts Hazardous Substance List: Paraffin (8002-74-2)
Pennsylvania: Pennsylvania Hazardous Substance List: Paraffin (8002-74-2)
International Regulations
Canada WHMIS: All ingredients in this product are listed on the Domestic Substance List (DSL).
Europe EINECS Numbers: Paraffin (8002-74-2): EINECS#: 232-315-6. Microcrystalline Wax (63231-60-7): EINECS#: 264-038-1. Hydrocarbon Resin (6472-16-1): EINECS#: 265-116-8. Butylated Hydroxy Toluene (128-37-0): EINECS#: 204-881-4.
Section 16: Other Information
Label Information: ND
European Risk and Safety Phrases: ND
European symbols needed: ND
Canadian WHMIS Symbols: ND
HMIS® Hazard Rating: Health: 1; Fire: 1; Reactivity: 0
NFPA Hazard Rating: Health: 1; Fire: 1; Reactivity: 0
(0=least, 1=Slight, 2=Moderate, 3=High, 4=Extreme)
Abbreviations used in this document
NE= Not established
NA= Not applicable
NIF= No Information Found
ND= No Data
Disclaimer
Ted Pella, Inc. makes no warranty of any kind regarding the information
furnished herein. Users should independently determine the suitability and
completeness of information from all sources. While this data is presented in
good faith and believed to be accurate, it should be considered only as a
supplement to other information gathered by the user. It is the User's
responsibility to assure the proper use and disposal of these materials as well
as the safety and health of all personnel who may work with or otherwise come
in contact with these materials.
MSDS Form 0013F1 V2