Material Safety Data Sheet
Product No. 18107 N, N- Benzyldimethylamine, BDMA, Component of Poly/Bed® Test Kit
Issue Date (10-23-06)
Review Date (06-18-07)
Section 1: Product and Company Identification
Product Name: N, N- Benzyldimethylamine
Synonym: Synonym: N,N-Dimethylbenzenemethanamine, N-Benzyldimethylamine, Dimethylbenzylamine, Benzyl-N,N-dimethylamine, N-(Phenylmethyl)dimethylamine, Benzyldimethylamine, BDMA, Sumine 2015
Chemical Family: Aralkyl Amine
Company Name
Ted Pella, Inc. and PELCO International, P.O. Box 492477, Redding, CA
96049-2477
Domestic Phone (800) 237-3526 (Mon-Thu. 6:00AM to 4:30PM PST; Fri 6:00AM
to 4:00PM PST)
International Phone (01) (530) 243-2200 (Mon-Thu. 6:00AM to 4:30PM PST; Fri 6:00AM to 4:00PM PST)
Chemtrec Emergency Number 1-800-424-9300 24 hrs a day.
Section 2: Composition / Information on Ingredients
|
Principle Hazardous Component(s)
|
% |
OSHA mg/m3 |
ACGIH |
NTP |
IARC |
OSHA |
|
Benzyldimethylamine (103-83-3) |
100 |
NE |
NE |
ND |
ND |
ND |
Section 3: Hazard Identification
Emergency overview
Appearance: Colorless to light yellow liquid.
Immediate effects: Corrosive. Combustible liquid. A possible skin sensitizer. Toxic by inhalation, in contact with skin and if swallowed causes burns. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Potential health effects
Primary Routes of entry: Inhalation, ingestion and skin contact.
Signs and Symptoms of Overexposure: ND
Eyes: Severely irritating to the eyes.
Skin: Corrosive, contact with skin may result in strong irritation and burns.
Ingestion: May be harmful if swallowed and causes burns.
Inhalation: Breathing vapors or mist will cause irritation to the respiratory tracts and mucous membrane.
Chronic Exposure: ND
Chemical Listed As Carcinogen Or Potential Carcinogen: No
See Toxicological Information (Section11)
Potential environmental effects
See Ecological Information (Section 12)
Section 4: First Aid Measures
If accidental overexposure is suspected
Eye(s) Contact: Immediately flush eyes withy plenty of water for at least 15 minutes, holding eyelids apart. Get medical attention if irritation or other symptoms occur.
Skin Contact: Immediately flush eyes withy plenty of water for at least 15
minutes. Use soap if available. Remove contaminated clothing or shoes after
flushing has began. Get prompt medical attention. Thoroughly was
contaminated clothing and shoes or discard in a manner
Inhalation: Remove to fresh air. If not breathing give artificial respiration
or give oxygen by trained personal. Seek immediate medical attention.
Ingestion: Dilute with milk or water. Get immediate medical attention. Never give anything by mouth to an unconscious person.
Note to physician
Treatment: ND
Medical Conditions generally Aggravated by Exposure: ND
Section 5: Fire Fighting Measures
Flash Point: 135.0º F ( 57.2º C) Open
cup
Flammable Limits: ND
Auto-ignition point: ND
Fire Extinguishing Media: CO2, dry chemical, alcohol foam, water
spray.
Special Fire Fighting Procedures: Evacuate area and fight from safe distance.
Wear self contained breathing apparatus pressure demand (MSHA/NIOSH approved or
equivalent) and full protective gear. Can burn in fire releasing toxic vapors.
Unusual Fire and Explosion Hazards: Vapors may travel a considerable distance
and flashback to the source.
Hazardous combustion products: Emits toxic fumes under fire conditions.
DOT Class: Corrosive, flammable liquid.
Section 6: Accidental Release Measures
Steps to be Taken in Case Material is Released or Spilled: This material should
be prevented from contaminating soil or from entering sewage and drainage
systems and bodies of water. Isolate hazard area. Keep unnecessary and
unprotected personnel from entering. Prevent skin and eye contact. See Section
8. For small spills: Absorb spill with inert material (e.g., dry sand or
vermiculite) then place in a chemical storage container for disposal. For large
spill: Shut of leak, if safe to do so. Clean up spills immediately, observing
precautions in protective equipment section, see Section 8. Contain spilled
liquid with sand, vermiculite or earth. Retain all contaminated water for
removal and treatment.
Waste Disposal Methods: Dispose of waste according to Federal, State and Local
Regulations.
Section 7: Handling and Storage
Precautions to be Taken in Handling and Storage: Use with adequate ventilation.
Wash thoroughly after handling. Follow all MSDS/label precautions even after
container is emptied because they may contain residues. Avoid contact with eyes
and skin. Avoid breathing vapors. Keep away from ignition sources. Store in
accordance with OSHA regulations and NEPA guidelines. Keep container closed
when not in use.
Storage temperature: Room temperature.
Storage Pressure: ND
Section 8: Exposure Controls / Personal Protection
Engineering Controls
Ventilation required: Use fume hood. Use process enclosures, local exhaust ventilation, or other engineering controls to control sources of dust, mist or vapor.
Personal Protection Equipment
Respiratory protection: Use a NIOSH/MSHA approved air purifying respirator as needed to control exposure. Consult with respirator manufacturer to determine respirator selection, use and limitations. Use a positive pressure air supplied respirator for uncontrolled releases or when air purifying respirator limitations may be exceeded. Follow respiratory protection program requirements (OSHA 1910.134 and ANSI Z88.2) for all respirator use.
Protective gloves: Wear impervious gloves.
Skin protection: Wear chemical protective clothing, overalls, aprons or boots
as need to prevent contact with skin.
Eye protection: Wear splash-proof chemical goggles and a face shield.
Additional clothing and/or equipment: Eyewash stations or shower
Exposure Guidelines
See Composition/Information on Ingredients (Section2)
Section 9 Physical and Chemical Properties
Appearance and Physical State: Colorless to light yellow liquid.
Odor (threshold): Amine.
Specific Gravity (H2O=1): 0.91.
Vapor Pressure (mm Hg): 1.8
Vapor Density (air=1): ND
Percent Volatile by volume: ND
Evaporation Rate (butyl acetate=1): ND
Boiling Point: 349.0º F or 176.1º C
Freezing point / melting point: ND
pH: ND
Solubility in Water: Slightly
Formula: C9H13N
Section 10: Stability and Reactivity
Stability: Stable
Conditions to Avoid: Exposure to oxidizing agents and acids. Prolong exposure
to heat.
Materials to Avoid (Incompatibility): Strong oxidizing agents, acids, acid
anhydrides, acid chlorides.
Hazardous Decomposition Products: Carbon dioxide, carbon monoxide and nitrogen
oxides.
Hazardous Polymerization: Not prone to hazardous polymerization.
Section 11: Toxicological Information
Results of component toxicity test performed: BDMA: Oral (rat) LD50: 650 mg/kg, Dermal (rabbit) LD50: 1660 mg/kg, Inhalation (rat) LC50: 373 ppm/4 hr, Skin Irritancy, rabbit: 500 mg/4 hr- severe with local necrosis. Eye Irritancy, rabbit: 5 mg severe.
Human experience: ND
This product does not contain any compounds listed by NTP or IARC or regulated by OSHA as a carcinogen.
Section 12: Ecological Information
Ecological Information: Acute Ecotoxicity Test: Test type: LC50 Fish (Pimephales promelas or Fathead minnow):35.8-39.90 mg /L – 96 hr. Test type: LC50 (Leuciscus idus): 10-22 mg/L – 96 hr
Chemical Fate Information: ND
Section 13 Disposal Considerations
RCRA 40 CFR 261 Classification: ND
Federal, State and local laws governing disposal of materials can differ. Ensure proper disposal compliance with proper authorities before disposal.
Section 14: Transportation Information
US DOT Information: Proper shipping name: Benzyldimethylamine
Hazard Class: 8, 3
Packaging group: II
UN Number: UN2619
IATA: Proper shipping name: Benzyldimethylamine
Hazard Class: 8, 3
Packing group: II
UN Number: UN2919
IMO: Proper shipping name: Benzyldimethylamine
Class: 8, 3
UN Number: UN2919
Packing group: II
Marine Pollutant: No
Canadian TDG: Proper shipping name: Benzyldimethylamine
Section 15: Regulatory Information
United States Federal Regulations
MSDS complies with OSHA’s Hazard Communication Rule 29, CFR 1910.1200.
SARA Title III: Section 311/312: Chronic health hazard; No. Acute health hazard: Yes. Fire hazard: Yes. Sudden pressure: No. Reactivity hazard: No. Section 302: Extremely hazardous ingredients: None. Section 313 Toxic chemical ingredients: None.
RCRA: ND
TSCA: Reported in TSCA inventory
CERCLA: Nome
State Regulations
California Proposition 65: None
NJ environmental Hazard Substance List, ingredients: None
International Regulations
Canada WHMIS: DSL: Yes, NDSL: No
Europe EINECS Numbers: EC NO: 203-149-1, EC Index NO: 612-074-00-7
OEL = MAK
OEL-Russia: STEL 5 mg/M3, Jan 1993
Section 16: Other Information
Label Information: Corrosive, Flammable
European Risk and Safety Phrases: R10 Flammable, R20/21/22 Harmful by inhalation, in contact with skin and if swallowed. R34 Cause burns. R52/53 Harmful to aquatic organisms may cause long-term adverse effects in the aquatic environment. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36 Wear suitable protective clothing. S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S61 Avoid release to the environment. Refer to special instructions/safety data sheets
European symbols needed: ND
Canadian WHMIS Symbols: ND
HMIS® Hazard Rating: Health: 3; Flammability: 2; Physical Hazard: 0 Personal Protection: See Section 8
NFPA Hazard Rating: Health: 3; Fire: 2; Reactivity: 0
(0=least, 1=Slight, 2=Moderate, 3=High, 4=Extreme)
Abbreviations used in this document
NE= Not established
NA= Not applicable
NIF= No Information Found
ND= No Data
Disclaimer
Ted Pella, Inc. makes no warranty of any kind regarding the information
furnished herein. Users should independently determine the suitability and
completeness of information from all sources. While this data is presented in
good faith and believed to be accurate, it should be considered only as a
supplement to other information gathered by the user. It is the User's
responsibility to assure the proper use and disposal of these materials as well
as the safety and health of all personnel who may work with or otherwise come
in contact with these materials.
MSDS Form 0013F1 V2