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Material Safety Data Sheet

Prod. No. 18097 (Component of GMA Kit No. 18350): Benzoyl Peroxide Paste
Issue Date (07-17-00)


Section 1: Product and Company Identification
Product Name: Benzoyl Peroxide Paste

Common Names/Synonyms: Benzoyl Peroxide in Dibutyl Phthalate
Chemical family: Organic peroxides/Diacyl peroxide
TSCA Inventory: Acceptable mixture
Formula: Cl4H10O3+C16H22O4
Company Name
Ted Pella, Inc. and PELCO International, P.O. Box 492477, Redding, CA 96049-2477
Domestic Phone  (800) 237-3526 (Mon-Thu. 6:00AM to 4:30PM PST; Fri 6:00AM to 4:00PM PST)
International Phone (01) (530) 243-2200 (Mon-Thu. 6:00AM to 4:30PM PST; Fri 6:00AM to 4:00PM PST)
Chemtrec Emergency Number 1-800-424-9300 24 hrs a day.
Section 2 Shipping Data:
DOT Shipping Name: Benzoyl Peroxide, 50% as a paste
DOT Hazard Classification: Organic peroxide
IMCO Class: 5.2
UN No: NA
NA No: NA
Data No.: NA
Corrosive per DOT:
To Skin: NA
To Steel: NA

Section 3 Hazardous Ingredients:

Cas No.:

Components: % ACGIH TLV OSHA PEL 

 PPM or *mg/M3

94-36-0 

Benzoyl Peroxide
Peroxide

~50

5

5

84-74-2 

Dibutyl Phthalate (DBP)

~50

5*

5*

Carcinogen Reference Applies Above: NA

Section 4 Physical Data:
Initial Boiling Point: NA
Melting/Freezing Point: NA
Pour Point: NA
Molecular Weight: NA
Specific Gravity (H2O=1): NE
Vapor Pressure mmHg: NA
Vapor Density (Air=1): ND
Solubility in Water: Insoluble (% by weight)
% Volatiles by Weight: NA
Evaporation Rate: ND (Butyl Acetate = 1)
Appearance and Odor: Thick, white paste with a slight odor

Section 5 Fire and Explosion Hazard Data:
Flash Point (test method): NA
Flammable Limits in Air: NA
Autoignition Temperature: NA
DOT Emergency Guide No.: 48
Extinguishing Media: Water fog or spray, CO2 Dry Chemical, Foam.
Special Fire Fighting Procedures: Evacuate area and apply water from a safe distance. Spray water on the nearby peroxide containers to prevent overheating.
Unusual Fire and Explosion Hazards: Peroxides and decomposition products are flammable and can ignite with explosive force if confined.

Section 6 Reactivity Data:
Stability: Unstable
Conditions Contributing to Instability: Thermal decomposition contamination
Hazardous Polymerization: Will Not Occur.
Incompatibility (avoid contact with): Strong acids, strong alkalis, strong oxidizers, reducing agents, sulfur accelerators and metal salts.
Hazardous Decomposition Products thermal and other/list:
On decomposition, Benzoyl Peroxide paste can produce flammable & toxic vapors & PCB's (2,2' ,4, 4' Tetrachlorobiphenyl)
Conditions to Avoid: Ignition sources, temperatures above 40°C (104°F)
Recommended Maximum Storage Temperature: 30°C (86°F)

Section 7 Spill or Leak Procedures:
Steps to be taken if material is released or spilled:
Avoid skin contact. Flush with water. Sweep or scoop out and remove.
Wet with water and remove with non-sparking tools.
Waste Disposal: Consult Federal, State and Local authorities for proper disposal procedures.
Under RCRA this product is classified as: Reactive
Under CERCLA (Superfund): Reportable Quantity: RQ = 1000 pounds
Thoroughly rinse empty containers. Based on Dibutylphthalate.

Section 8 Toxicity:
Acute:
Dermal (skin): LD50: >8000 mg/kg (rabbits 50% peroxide in Dibutyl Phthalate). Not a toxic substance by dermal route.
Eye: Draize Score-Unknown. "Not an eye irritant" (based on rabbit tests with 50% peroxide in Dibutyl Phthalate).
Inhalation: LC50: ND
Oral: LD50: >12,918 mg/kg (rats 50% peroxide in Dibutyl Phthalate). Not a toxic substance by oral route.
Other: NA.

Section 9 Health Hazard Information:
Effects of Overexposure:
Dermal: Prolonged skin contact may cause skin irritation and redness.
Eye: Contact may cause eye irritation and/or damage.
Inhalation: May cause irritation of the nose, throat, and lungs.
Ingestion: May cause toxic effects.
Emergency First Aid:
Dermal: Remove contaminated clothing immediately. Wash affected skin thoroughly with soap and water. Seek medical attention if indicated. Launder clothing before reuse.
Eye Contact: Immediately flush with water for at least 15 minutes.
Contact lenses should be removed if the initial flush doesn't wash them out. Get medical attention.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. Give oxygen if needed. Get medical attention.
Ingestion: (Never give anything by mouth to an unconscious person):
Do not induce vomiting. Give plenty of water. Get medical attention. Get medical aid immediately. Contact local poison control center. Rinse mouth.

Section 9 Special Protection Information:
Hands: Neoprene, nitrile rubber, polyvinyl alcohol gloves.
Eyes: Eye protection must be worn.
Ventilation: Sufficient to prevent accumulation of vapors or particulates.
Respirator Type: For reducing contaminant concentration in inhaled air: Filter - dust, fume, mist.
Other: Safety shower and/or eye wash should be available. Chemical-resistant apron or coveralls may be needed.

Section 10 Special Precautions:
Do not store near combustibles.
Wash thoroughly after handling.
Do not get in eyes, on skin or clothing.
Do not breathe dust, vapor, mist, gas.
Keep container closed.
Empty container may contain hazardous residues.
Keep away from heat, sparks and open flames.
Use explosion proof equipment.
Keep away from all sources of heat and ignition such as radiators, steam pipes and direct sunlight.

Section 11 Other Information:
For more safety data, see NFPA Bulletin 43B "Storage of Organic Peroxide Formulations".
Store in original containers. Select storage areas in accordance with local laws and regulations.

Note:
NA = Not Applicable
< = Less Than
~ = Approximately
ND = Not Determined
> = Greater Than


Ted Pella, Inc. makes no warranty of any kind regarding the information furnished herein. Users should independently determine the suitability and completeness of information from all sources. While this data is presented in good faith and believed to be accurate, it should be considered only as a supplement to other information gathered by the user. It is the User's responsibility to assure the proper use and disposal of these materials as well as the safety and health of all personnel who may work with or otherwise come in contact with these materials