Material Safety Data Sheet

Product No. 18042 DMP-30, DMP-30 Kit Components

Issue Date (10-24-07)

Review Date (01-26-09)

Section 1: Product and Company Identification

Product Name: DMP-30

Synonym: None

Chemical Family: Mannich Base

Intended Use: Curing agent, epoxy

Company Name

Ted Pella, Inc. and PELCO International, P.O. Box 492477, Redding, CA 96049-2477
Domestic Phone  (800) 237-3526 (Mon-Thu. 6:00AM to 4:30PM PST; Fri 6:00AM to 4:00PM PST)

International Phone (01) (530) 243-2200 (Mon-Thu. 6:00AM to 4:30PM PST; Fri 6:00AM to 4:00PM PST)

Chemtrec Emergency Number 1-800-424-9300 24 hrs a day.

Section 2: Composition / Information on Ingredients

Principle Hazardous Component(s) (chemical and common name(s)) (Cas. No)	%	OSHA PEL mg/m3	ACGIH  TLV mg/m3	NTP	IARC	OSHA regulated
Tris-2,4,6-(Dimethylaminomethyl) phenol (90-72-2)	> 85	NE	NE	No	No	No
The remaining components are trade secret (Cas. No. Unknown)	ND	ND	ND	ND	ND	ND

Exposure Standards: No standards established for the product. Maintain air contaminant concentrations in the workplace at the lowest feasible levels.

Section 3: Hazard Identification
Emergency overview

Appearance: Straw, yellow mobile liquid.

Immediate effects: Harmful if swallowed. Corrosive to eyes and skin. Severe eye and skin irritant. Severe respiratory tract.

Potential health effects

Primary Routes of entry: Eye contact and skin contact, ingestion, skin absorption, and inhalation.
Signs and Symptoms of Overexposure:
Eyes: Product vapor in low concentrations can cause lacrimation, conjunctivitis and corneal edema when absorbed into the tissue of the eye from the atmosphere. Corneal edema may give rise to a perception of 'blue haze'' or “fog'' around lights. The effect is transient and has no known residual effect. Burns of the eye may cause blindness.

Skin: Contact of undiluted product with the skin quickly causes severe irritation and pain and may cause burns, necrosis and permanent injury. Product is absorbed through the skin and may cause nausea, headache and general discomfort.

Ingestion: Ingestion may cause death unless treated promptly.

Inhalation: Inhalation of aerosols and mists may severely damage contacted tissue and produce scarring.

Chronic Exposure: Repeated and/or prolonged exposures may result in: nervous system disorders (such as narcosis, behavioral changes or decrease in motor function), adverse respiratory effects (such as cough, tightness of chest or shortness of breath), adverse eye effects (such as conjunctivitis or corneal damage), muscular dysfunction, adverse skin effects (such as rash, irritation or corrosion).

Chemical Listed As Carcinogen Or Potential Carcinogen: This product contains no carcinogens in concentrations of 0.1 percent or greater.

See Toxicological Information (Section11)

Potential environmental effects

See Ecological Information (Section 12)

Section 4: First Aid Measures
If accidental overexposure is suspected

Eye(s) Contact: Hold eyelids apart and immediately flush eyes with plenty of water for at least 15 minutes. Seek medical advice.

Skin Contact: Remove product and immediately flush affected area with water for at least 15 minutes. Remove contaminated clothing and shoes. Destroy contaminated leather apparel. Cover the affected area with a sterile dressing or clean sheeting and transport for medical care. DO NOT APPLY GREASES OR OINTMENTS. Control shock, if present. Wash contaminated clothing prior to reuse.
Inhalation: Move patient to fresh air. If breathing has stopped or is labored give assisted respiration (e.g. mouth-to-mouth). Prevent aspiration of vomit. Turn victim's head to the side. Seek medical advice.

Ingestion: In the event of ingestion, administer 3-4 glasses of milk or water. DO NOT INDUCE VOMITING. Seek medical advice.

Note to physician

Treatment: ND

Medical Conditions generally Aggravated by Exposure: Asthma, chronic respiratory disease (e.g. Bronchitis, Emphysema), eye disease, neurological disorders, skin disorders and allergies.

Section 5: Fire Fighting Measures
Flash Point: 148.89 °C (300 °F)
Flammable Limits: ND

Auto-ignition point: ND

Fire Hazard Classification (OSHA/NFPA): Class III B
Fire Extinguishing Media: Ignition will give rise to a Class B fire. Large Use: Alcohol foam, water spray. Small fire use: Carbon dioxide (CO2), dry chemical, dry sand or limestone.
Special Fire Fighting Procedures: A face shield should be worn. Firefighters should wear butyl rubber boots, gloves and body suit and a self-contained breathing apparatus. Retain expended liquids from fire fighting for later disposal. Personnel in vicinity and downwind should be evacuated.
Unusual Fire and Explosion Hazards: ND

Hazardous combustion products: May generate toxic or irritating combustion products. Also, may generate the following toxic gases: carbon monoxide, toxic nitrogen oxide, and ammonia.

DOT Class: Amines, liquid, corrosive, n.o.s. (Tris-2,4,6-[Dimethylaminomethyl]phenol)

Section 6: Accidental Release Measures
Steps to be Taken in Case Material is Released or Spilled: Shut off or remove all ignition sources. Stop the leak, if possible. Construct a dike to prevent spreading. Reduce vapor spreading with a water spray. If recovery is not feasible, admix with dry soil, sand or non-reactive absorbent (sodium bisulfate) and place in a container or dumpster pending disposal. Transfer to containers by suction, preparatory for later disposal. Place in metal containers for recovery or disposal. Flush area with water spray. Clean-up personnel must be equipped with self contained breathing apparatus and butyl rubber protective clothing. Large Spills: recover spilled materials with a vacuum truck.
Waste Disposal Methods: Dispose of waste according to Federal, State and Local Regulations.

Section 7: Handling and Storage
Precautions to be Taken in Handling and Storage: Keep in cool, dry, ventilated storage and in closed containers. Store in steel containers preferably located outdoors, above ground, and surrounded by dikes to contain spills or leaks. Do not store in iron or other reactive metals containers. Recommended suitable container materials include plastic, stainless, and carbon steels. Avoid contact with skin or eyes. Avoid breathing of vapors. Handle in well ventilated work space.

Storage temperature: ND

Storage Pressure: ND

Section 8: Exposure Controls / Personal Protection
Engineering Controls

Ventilation required: No specific controls needed, but general mechanical exhaust required.

Personal Protection Equipment

Respiratory protection: Not required under normal conditions in a well-ventilated workplace.

Protective gloves: Impermeable gloves made of: neoprene, cuffed butyl, or nitrile.
Skin protection: Impervious clothing: Slicker Suit, rubber boots, and full rubber suit (rain gear). Butyl or latex protective clothing.
Eye protection: Full face shield with goggles underneath.
Additional clothing and/or equipment: Provide readily accessible eye wash stations and safety showers.

Exposure Guidelines

See Composition/Information on Ingredients (Section2)

Section 9 Physical and Chemical Properties
Appearance and Physical State: Straw yellow, mobile liquid.

Odor (threshold): Irritating

Specific Gravity (H2O=1): 0.97

Vapor Pressure (mm Hg): > 0.01 @ 21 °C (70 °F)

Vapor Density (air=1): ND

Percent Volatile by volume: ND

 

Evaporation Rate (butyl acetate=1): ND

Boiling Point:  >100.0 °C (> 212 °F)

Freezing point / melting point: ND
pH: Alkaline
Solubility in Water: 80 %
Molecular Weight: Mixture

Section 10: Stability and Reactivity
Stability: Stable
Conditions to Avoid: NA

Materials to Avoid (Incompatibility): Mineral acids (i.e. sulfuric, phosphoric, etc.). Organic acids (i.e. acetic acid, citric acid etc.). Oxidizing agents (i.e. per chlorates, nitrates etc.). Sodium or Calcium Hypochlorite. Product slowly corrodes copper, aluminum, zinc and galvanized surfaces. Reaction with peroxides may result in violent decomposition of peroxide possibly creating an explosion. A reaction accompanied by large heat release occurs when the product is mixed with acids. Heat generated may be sufficient to cause vigorous boiling creating a hazard due to splashing or splattering of hot material.
Hazardous Decomposition Products: Irritating and toxic fumes at elevated temperatures. Nitric acid in a

fire. Nitrogen oxide can react with water vapors to form corrosive nitric acid (TLV=2 ppm).
Hazardous Polymerization: Will not occur

Section 11: Toxicological Information

Results of component toxicity test performed: Acute Oral Toxicity: (Rat) LD50 = 1670.00 mg/kg

Irritation Effects Data: Corrosive to the skin of a rabbit.

Chronic/Subchronic Data: Subchronic exposure of this material or component in test animals has caused abnormalities in the following organs; however these effects are not sufficient to characterize the material as a specific organ toxin: Central nervous system. This product has been tested and shown not to cause sensitization in guinea pigs.

Human experience: ND

This product does not contain any compounds listed by NTP or IARC or regulated by OSHA as a carcinogen.

Section 12: Ecological Information

Ecological Information: Rainbow trout (Salmo gairdneri) 96 hour T L50 =180-240 mg/l

Chemical Fate Information: ND

Section 13 Disposal Considerations

RCRA 40 CFR 261 Classification: Waste from this product may present long term environmental hazards, thus landfill disposal must be considered less acceptable than incineration.

Federal, State and local laws governing disposal of materials can differ. Ensure proper disposal compliance with proper authorities before disposal.

Section 14: Transportation Information

US DOT Information: Proper shipping name: Amines, liquid, corrosive, n.o.s. (Tris-2,4,6-[Dimethylaminomethyl]phenol)

Hazard Class: 8

Packaging group: III

UN Number: UN2735

Limitations: ND

IATA: Proper shipping name:  Amines, liquid, corrosive, n.o.s. (Tris-2,4,6-[Dimethylaminomethyl]phenol)

Hazard Class: 8

Packing group: III

UN Number: UN2735

Limitations: Shipment per 49 CFR 171.11

Domestic shipments only:

IMO: Proper shipping name: Amines, liquid, corrosive, n.o.s. (Tris-2,4,6-[Dimethylaminomethyl]phenol)

Class: 8

UN Number: UN2735

Packing group: III

EMS: 8-05

MFAG: 320

Marine Pollutant: No

Canadian TDG: ND

IMDG Page: ND

Limitations: ND

Section 15: Regulatory Information

United States Federal Regulations

MSDS complies with OSHA’s Hazard Communication Rule 29, CFR 1910.1200.

SARA: Yes

SARA Title III: Defined in Section 313: Immediate Health Hazard. "De minimis" Levels: None.

RCRA: ND

TSCA: All components are included in the EPA Toxic Substances Control Act (TSCA) Chemical Substance Inventory.

CERCLA: ND

State Regulations

California Proposition 65: None listed

New Jersey Trade Secret Registry Number(s): 05995500-(HK54-U)

International Regulations

Canada WHMIS: Materials in this product are listed on the CPR inventory list. DSL: Included on inventory.

Europe EINECS Numbers: (Tris-2,4,6-[Dimethylaminomethyl]phenol) (90-72-2): EINECS#: 202-013-9

Section 16: Other Information

Label Information: Harmful

European Risk and Safety Phrases: Irritating to eyes and skin (R26/39). Harmful if swallowed (R22). In case of contact with eyes, rinse immediately with plenty of water and seek medical advice (S26). After contact with skin, wash immediately with plenty of soap and water (S28).

European symbols needed: XN

Canadian WHMIS Symbols: Class E Corrosive. Test tube/hand.

HMIS® Hazard Rating: Health: 3; Flammability 1; Physical Hazard: 0
(0=least, 1=Slight, 2=Moderate, 3=High, 4=Extreme)

Abbreviations used in this document

NE= Not established

NA= Not applicable

NIF= No Information Found

ND= No Data

Disclaimer
Ted Pella, Inc. makes no warranty of any kind regarding the information furnished herein. Users should independently determine the suitability and completeness of information from all sources. While this data is presented in good faith and believed to be accurate, it should be considered only as a supplement to other information gathered by the user. It is the User's responsibility to assure the proper use and disposal of these materials as well as the safety and health of all personnel who may work with or otherwise come in contact with these materials.

 

MSDS Form 0013F1 V2