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Section 3 Hazardous Components:
Component: 3-AMINOPROPYLTRIETHOXYSILANE
CAS Number: 919-30-2
SARA313: No
EC no: 213-048-4.
Annex Index Number: 612-108-00-0
Emergency Overview: Corrosive. Harmful if swallowed. Causes burns. Target organ(3): Nerves. Liver
HMIS Rating: Health: 3*; Flammability: 1; Reactivity: 1
NFPA Rating: Health: 3; Flammability: 1; Reactivity: 1
*additional chronic hazards present.

Section 4 Fire and Explosion Hazard Data:
Flash Point: 208.4° F, 98° C; Method: Closed cup
Autoignition Temperature: N/A
Explosion Limits: Lower: 0.8%; Upper: 4.5%
Flammability: N/A
Fire Extinguishing Media: Carbon dioxide, dry chemical powder, or appropriate foam.
Unsuitable: Do not use water.
Fire Fighting Protective Equipment: Wear self contained breathing apparatus and protective clothing to prevent contact with skin and eyes.
Specific Hazard(s): Emits toxic fumes under fire conditions.

Section 5 Effects of Overexposure
Acute Effects
Eye contact: Causes burns.
Skin contact: Causes burns.
Skin adsorption: My be harmful if adsorbed through the skin
Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled.
Ingestion: Harmful if swallowed
Target organs: Nerves. Liver.
Signs and symptoms of exposure: Materials is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes and skin. Inhalation may result in spasm, inflammation and edema of the larynx and bronchi, chemical pneumonitis and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting.
RTECS number: TX2100000
Toxicity Data:
Oral - Rat: 1780 mg/kg (LD50)
Oral - Mouse: 4000 mg/kg (LD50)
Remarks: Behavioral: Excitement.
Lungs, thorax or respiration: emphysema
Blood: Changes in leukocyte (WBC) count.
Irritation Data: Skin - Rabbit: 0.1 mg 24 H
Remarks: Open irritation test
Skin - Rabbit: 5 mg 24H
Remarks: Severe irritation effect
Eyes - Rabbit: 100 mg
Remarks: Mild irritation effect
Eyes - Rabbit: 0.75 mg 24H
Remarks: Severe irritation effect

Section 6 Emergency First Aid Procedures:
Oral Exposure: If swallowed, wash out mouth with water provided person is conscious. Call a physician. Do not induce vomiting.
Inhalation Exposure: If inhaled, remove to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen.
Dermal Exposure: In case of skin contact, flush with copious amounts of water for at least 15 minutes. Remove contaminated clothing and shoes. Call a physician.
Eye Exposure: Incase of contact with eyes, flush with copious amounts of water for at least 15 minutes. Assure adequate flushing by separating the eyelids with fingers. Call a physician.

Section 7 Reactivity Data:
Stability: Stable.
Conditions of instability: May decompose on exposure to moist air or water.
Incompatibilities (materials to avoid): Strong oxidizing agents
Hazardous Polymerization: Will not occur.
Hazardous Decomposition Products: Thermal decomposition may produce carbon monoxide, carbon dioxide and nitrogen oxides, silicon oxide.

Section 8 Protective Equipment for Routine Handling and Spill Cleanup:
Engineering controls: Safety shower and eye bath. Use only in a chemical fume hood.
Personal Protective Equipment:
Respiratory: Government approved respirator.
Hand: Compatible chemical-resistant gloves.
Eye: Chemical safety goggles
Other: Face shield (8-inch minimum).
General hygiene measures: Wash contaminated clothing before reuse. Discard contaminated shoes. Wash thoroughly after handling.

Section 9 Accidental Release Measures:
Procedure to be followed in case of leak or spill: Evacuate area.
Procedure(s) of personal precaution(s): Wear self-contained breathing apparatus, rubber boots and heavy rubber gloves.
Methods for cleaning up: Cover with dry lime or soda ash, pick up, keep in a closed container and hold for waste disposal. Ventilate area and wash spill site after material pickup is complete.

Section 10 Disposal Considerations:
Contact a licensed professional waste disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. Observe all federal, state and local environmental regulations.

Section 11 Handling and Storage
User exposure: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure.
Storage suitable: Keep tightly closed. Store at 2-8°C
Special requirements: Moisture sensitive. Store under inert gas.

Section 12 Transport Information :
DOT:
Proper Shipping Name: Corrosive liquid, basic, organic, n.o.s.
UN#: 3267
Class: 8
Packing Group: II
Hazard Label: Corrosive
PIH: Not PIH

IATA:
Proper Shipping Name: Corrosive liquid, basic, organic, n.o.s
IATA UN Number: 3267
Hazard Class: 8
Packing Group: II

Section 13 Regulatory Information :
EU Directives Classification:
Symbol of Danger: C
Indication of Danger: Corrosive
Risk Statements: R: 22 34
Harmful if swallowed. Causes burns.
Safety Statements: S: 26 36/37/39 45
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

US Directives Classification:
Indication of Danger: Corrosive
Risk Statements: R: 22 34
Harmful if swallowed. Causes burns.
Safety Statements:
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible)
US Statements: Target organ(s): Nerves, liver.