Material Safety Data Sheet
Product No. 14462 PELCO® Pro F5 Cyanoacrylate Glue
Issue Date (10-02-03)
Review Date (09-16-09)
Section 1: Product and Company Identification
Product Name: PELCO® Pro F5 Cyanoacrylate Glue
Synonym: Super Glue, Instant Adhesive
Company Name
Ted Pella, Inc. and PELCO International, P.O. Box 492477, Redding, CA
96049-2477
Domestic Phone (800) 237-3526 (Mon-Thu. 6:00AM to 4:30PM PST; Fri 6:00AM
to 4:00PM PST)
International Phone (01) (530) 243-2200 (Mon-Thu. 6:00AM to 4:30PM PST; Fri 6:00AM to 4:00PM PST)
Chemtrec Emergency Number 1-800-424-9300 24 hrs a day.
Section 2: Composition / Information on Ingredients
|
Principle Hazardous Component(s)
|
% |
OSHA mg/m3 |
ACGIH |
NTP |
IARC |
OSHA |
|
Ethyl Cyanoacrylate (7085-85-0) |
90-99 |
ND |
ND |
No |
No |
No |
|
Poly Methyl Methacrylate (9011-14-7) |
1-10 |
ND |
ND |
No |
No |
No |
|
Hydroquinone (123-31-9) |
0.1-0.5 |
2 TWA |
ND |
No |
No |
No |
Section 3: Hazard Identification
Emergency overview
Appearance: Colorless liquid.
Immediate effects: Bonds skin rapidly and strongly.
Potential health effects
Primary Routes of entry: ND
Signs and Symptoms of Overexposure: Vapor is irritating to eyes and mucous
membranes above TLV. Prolonged and repeated overexposure to vapors may produce
allergic reactions with asthma like symptoms in sensitive individuals.
Eyes: Eye irritant. Vapor is irritating to eyes.
Skin: skin irritant.
Ingestion: It is almost impossible to swallow Cyanoacrylate. The adhesive solidifies and adheres in the mouth.
Inhalation: Vapor is irritating mucous membranes above TLV.
Chronic Exposure: ND
Chemical Listed As Carcinogen Or Potential Carcinogen: None
See Toxicological Information (Section11)
Potential environmental effects
See Ecological Information (Section 12)
Section 4: First Aid Measures
If accidental overexposure is suspected
Eye(s) Contact: Eyelid to eyelid or eyeball adhesion: In the event that eyelids are stuck together or bonded to the eyeball, wash thoroughly with warm water and apply a gauze patch. The eye will open without further action, typically in one to four days. There will be no residual damage. DO NOT try to open eyes by manipulation. Let the natural cleansing action of the eye take place. Adhesive on the eyeball: Cyanoacrylate introduced into the eyes will attach itself to the eye protein and will disassociate from it over intermittent periods, generally covering several hours. This will cause periods of tearing until clearance is achieved. The adhesive residue will flush out of the eye normally in a matter of hours, even with gross contamination.
Skin Contact: Skin Adhesion:
First immerse the bonded surface in warm soapy water. Peel or roll the surface
apart with the aid of a blunt edge. (pencil, spoon handle, etc.), then remove
the adhesive from the skin with soap and water. DO NOT try to pull surfaces
apart with a direct opposing action. Burns:Cyanoacrylates
give off heat on solidification. In rare cases a large amount will increase the
temperature enough to cause a burn. Should a burn occur, it should be treated
using normal medical procedures.
Inhalation: Remove to fresh air. Treat
symptomatically.
Ingestion: Mouth: If lips are accidentally stuck together, apply lots of warm water to the lips and encourage maximum wetting and pressure from saliva inside the mouth. Peel or roll lips apart. Do not try to pull the lips apart with a direct opposing action. It is almost impossible to swallow cyanoacrylate. The adhesive solidifies and adheres in the mouth. Saliva will lift the adhesive in 1 to 2 days
Note to physician
Treatment: ND
Medical Conditions generally Aggravated by Exposure: ND
Section 5: Fire Fighting Measures
Flash Point: 185° - 200°F
Flammable Limits: Lower ND. Upper ND.
Auto-ignition point: NIF
Fire Extinguishing Media: Carbon Dioxide, foam, dry chemical.
Special Fire Fighting Procedures: Wear self contained breathing apparatus and
protective clothing to prevent contact with skin, eyes, or inhalation of
vapors.
Unusual Fire and Explosion Hazards: Do not use cloth to wipe up spills. Use
water on spills to polymerize and then scrape up residue. Over exposure to
decomposition of products may be a health hazard
Hazardous combustion products: Irritating organic vapors
DOT Class: Unrestricted, combustible liquid.
Section 6: Accidental Release
Measures
Steps to be Taken in Case Material is Released or Spilled: Flood area with
water to polymerize (cure). Soak up with an inert absorbent.
Waste Disposal Methods: Dispose of waste according to Federal, State and Local Regulations. Recommended methods of disposal: Polymerize as above. Incinerate, or solid adhesive can be land filled in accordance with all applicable federal, state and local environmental regulations.
Section 7: Handling and
Storage
Precautions to be Taken in Handling and Storage: Store out of direct sunlight at or below 72°F to preserve shelf life. Handling: Avoid contact with eyes
and skin. Avoid breathing vapor.
Storage temperature: At or below 72°F
Storage Pressure: NA
Section 8: Exposure Controls / Personal Protection
Engineering Controls
Ventilation required: Local exhaust, cross air movement. Vent downwards, as vapors are heavier than air.
Personal Protection Equipment
Respiratory protection: Local exhaust, cross air movement
Protective gloves: Polyethylene.
Skin protection: Protective clothing.
Eye protection: Safety glasses.
Additional clothing and/or equipment: Eye bath and washing Station nearby.
Exposure Guidelines
See Composition/Information on Ingredients (Section2)
Section 9 Physical and Chemical Properties
Appearance and Physical State: Colorless liquid.
Odor (threshold): Slightly Pungent
Specific Gravity (H2O=1): 1.05
Vapor Pressure (mm Hg): ND
Vapor Density (air=1): Greater than one.
Percent Volatile by volume: ND
Evaporation Rate (butyl acetate=1): ND
Boiling Point: Greater than 150?F
Freezing point / melting point: ND
pH: NA
Solubility in Water: Polymerized by water.
Molecular Weight: NA
Section 10: Stability and Reactivity
Stability: Stable
Conditions to Avoid: Sunlight, moisture, heat.
Materials to Avoid
(Incompatibility): Polymerized by contact with water,
alcohols, amines, alkaline.
Hazardous Decomposition Products: None non-thermal,
Hazardous Polymerization: Will not occur.
Section 11: Toxicological Information
Results of component toxicity test performed: Estimated oral LD50 greater then 5,000 mg/kg. Estimated dermal LD50 greater than 2,000 mg/kg.
Human experience: ND
This product does not contain any compounds listed by NTP or IARC or regulated by OSHA as a carcinogen.
Section 12: Ecological Information
Ecological Information: ND
Chemical Fate Information: ND
Section 13 Disposal Considerations
RCRA 40 CFR 261 Classification: ND
Federal, State and local laws governing disposal of materials can differ. Ensure proper disposal compliance with proper authorities before disposal.
Section 14: Transportation Information
US DOT Information: Proper shipping name: Unrestricted, combustible liquid.
IATA: Proper shipping name: Unrestricted, combustible liquid.
IMO: Proper shipping name: Unrestricted, combustible liquid.
Marine Pollutant: NO
Canadian TDG: Unrestricted, combustible liquid
Section 15: Regulatory Information
United States Federal Regulations
MSDS complies with OSHA?s Hazard Communication Rule 29, CFR 1910.1200.
SARA: None
SARA Title III: None
RCRA: None
TSCA: All components listed
CERCLA: None
State Regulations
California Proposition 65: None
International Regulations
Canada WHMIS: ND
Europe EINECS Numbers: ND
Section 16: Other Information
Label Information: Irritant.
European Risk and Safety Phrases: ND
European symbols needed: ND
Canadian WHMIS Symbols: ND
HMIS Hazard Rating: Health: 2; Flammability: 2; Reactivity: 2
NFPA Hazard Rating: Health: 2; Fire 2; Reactivity: 2
(0=least, 1=Slight, 2=Moderate, 3=High, 4=Extreme)
Abbreviations used in this document
NE= Not established
NA= Not applicable
NIF= No Information Found
ND= No Data
Disclaimer
Ted Pella, Inc. makes no warranty of any kind regarding the information
furnished herein. Users should independently determine the suitability and
completeness of information from all sources. While this data is presented in
good faith and believed to be accurate, it should be considered only as a
supplement to other information gathered by the user. It is the User's
responsibility to assure the proper use and disposal of these materials as well
as the safety and health of all personnel who may work with or otherwise come
in contact with these materials.
MSDS Form 0013F1 V2