Prod. No. 14425, Aron Alpha #102
Issue Date (07-22-91)
Section 2 Physical Data:
Boiling Point (6mm Hg): 65°C
Freezing Point: Not available
Specific Gravity (H20=1): 1.10
Evaporation Rate, (n-BUAC=1): <1
Percent Volatiles: Negligible
pH at 25°C: Not available
Vapor Pressure (mm Hg): 0.25mm Hg (20°C)
Vapor Density (Air=1): >1
VOC Calculated: Negligible
Solubility in water : Negligible
Coefficient of water/oil Distrib.: Not Applicable
Appearance: Colorless liquid
Odor: Irritating
Odor Threshold, PPM: Not available
Section 3 Hazardous Ingredients Data:
The ingredients below have been associated with one or more of
the listed immediate and/or delayed (*) health hazards. Risk of
damage and effects depends upon duration and level of exposure.
BEFORE USING OR HANDLING, READ AND UNDERSTAND THE MSDS.
Signal Word CAUTION!
This material is a "health hazard" and/or a "physical
hazard" as determined when reviewed according to the requirements
of the Occupational Safety and Health Administration 29 CFR Part
1910.1200 "Hazard Communication" Standard.
Methyl 2-cyanoacrylate: (note revised OSHA PEL)
OSHA PEL: 2ppm (8 MG/M3 TWA; 4 PPM (16
MG/M3) STEL
ACGIH TLV: 2ppm (9.1 MG/M3) TWA; 4 PPM
(18 MG/M3) STEL
Carcinogen: Not listed by NTP, IARC or OSHA as of date of issuance
of this document.
Chemical Hazard rating: Health=2 (moderate), Fire=2 (moderate),
Reactivity=1 (slight)
Section 4 Fire and Explosion Hazard Data:
Combustible. Keep away from heat and flame.
Flash Point: 83°C
Auto Ignition Temp.: Not available
Flammable Limits (% by vol.): LEL 2.5; UEL No data
Fire Extinguishing Media: water spray, dry chemical, foam or CO2.
Use water to keep fire-exposed containers cool.
Unusual Fire and Explosion Hazards: None known
Section 5 Immediate Health Hazard Data:
Inhalation: May be harmful if inhaled. Liquid or vapor may cause
irritation of nose, throat and lungs.
Skin: Bonds skin instantly.
Skin Absorption: No hazards known
Eyes: Causes irritation
Ingestion: No hazards known
Section 6 Emergency First Aid Procedures:
Inhalation: Remove to fresh air. If not breathing, give artificial
respiration, preferably mouth-to-mouth. Call a physician.
Ingestion: If accidentally swallowed, dilute by drinking large
quantities of water. Immediately contact poison control center
or hospital emergency room for any other additional treatment
directions.
Skin Contact: If skin bonding occurs, peel, do not pull apart;
soak in nail polish remover containing acetone if necessary.
Eye Contact: If eye contact occurs, flush with water only for
15 minutes and GET MEDICAL ATTENTION. Do not use any solvents
to flush the eye and its surroundings.
Section 7 Reactivity Data:
Stability: Normally stable, but may become unstable at high temperatures
or may react with water.
Hazardous Polymerization: Will not occur.
Incompatibilities: Water, alcohols, amines, bases and direct UV.
Hazardous Decomposition Products: Oxides of Carbon
Other Hazards: None known
Section 8 Control Measures:
If airborne contaminants are generated when the material is heated
or handled, sufficient ventilation in volume and air flow patterns
should be provided to keep air contaminant concentration levels
below acceptable criteria.
Engineering Controls: The following exposure control techniques
may be used to effectively minimize employee exposure; local exhaust
ventilation, enclosed system design, process isolation and remote
control in combination with appropriate use of personal protective
equipment and prudent work practices. These techniques may not
necessarily address all issues pertaining to your operations.
We, therefore, recommend that you consult with experts of your
choice to determine whether or not your programs are adequate.
Section 9 Personal Protection Information:
Respiratory Protection: Where air contaminants can exceed acceptable
criteria, use NIOSH/MSHA approved respiratory protection equipment.
Respirators should be selected based on the form and concentration
of contaminants in air in accordance with OSHA 29 CFR 1910-.134
or other applicable standards or guidelines.
Protective Gloves: Wear impervious gloves as required to prevent
skin contact.
Eye Protection: Use goggles if contact is likely.
Section 10 Spill or Leak Procedures:
Eliminate all ignition sources.
Soak up with absorbent material and remove to a chemical disposal
area. Prevent entry into natural bodies of water.
Section 11 Waste Disposal:
Recover free liquid. Absorb residue and dispose of according to
local, state/provincial, and federal requirements.
Empty Container: May contain explosive vapors. DO NOT cut, puncture
or weld on or nearby.
Section 12 Handling Precautions:
Inhalation: Avoid breathing vapor.
Use with adequate ventilation.
Skin: Avoid contact with skin.
Eyes: Avoid contact with eyes.
Handle in accordance with good industrial hygiene and safety practices.
These practices include avoiding unnecessary exposure and removal
of the material from eyes, skin and clothing.
Wash thoroughly after handling.
Section 13 Storage Precautions:
Keep away from amines.
Store in cool, dry area away from sun and heat.
Keep containers tightly closed.
Exposure to small amounts of moisture, even moisture in air, causes
polymerization and renders the product unusable.
Keep away from heat, sparks, flame and other ignition sources.